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(1S 2S) - (-) - 1 2-Diphenyl-1 2-Ethanediamine （CAS # 29841-69-8) Ishusho Yerekanwe
  • (1S 2S) - (-) - 1 2-Diphenyl-1 2-Ethanediamine （CAS # 29841-69-8) 1

(1S 2S) - (-) - 1 2-Diphenyl-1 2-Ethanediamine （CAS # 29841-69-8)

Umutungo wa Shimi:

Inzira ya molekulari C14H16N2
Misa 212.29
Ubucucike 1.106 ± 0.06 g / cm3 (Biteganijwe)
Ingingo yo gushonga 83 ° C (Solv: ligroine (8032-32-4))
Ingingo ya Boling 115 ° C (Kanda: 5 Torr)
Flash point 199.9 ° C.
Amazi meza Kudashonga mumazi.
Umwuka 3.48E-05mmHg kuri 25 ° C.
Kugaragara Ikirahure kitagira ibara
pKa 9.78 ± 0.10 (Byahanuwe)
Imiterere y'Ububiko Ubushyuhe bw'icyumba
Yumva Yumva ikirere
Ironderero 1.619
MDL MFCD00082751
Ibintu bifatika na shimi Gushonga ingingo ya 83-85 ° C (lit.) Guhinduranya optique -104 o (c = 1.1, MeOH 25 oC)
indangantego -103 ° (C = 1, EtOH)
Imiterere yo kubika 2-8 ° C.

Umwuka Wumva
BRN 3201645

urushinge rutagira ibara rumeze nka kirisiti, nta mpumuro nziza, idashonga mumazi, gushonga muri methanol, Ethanol, okiside yoroshye mukirere.
Koresha Porogaramu ikoreshwa cyane muri synthesis ya asimmetricike no gukemura neza, nka hydroxylation ya asimmetric hydroxylation ya olefine, reaction ya asimmetric aldol, reaction ya asimmetric Diels-Alder reaction, asimmetric allylation reaction ya karubone, synthesis ya allylene alcool na propynyl alcool, asimmetric opoxidation. udafite amatsinda akora, gukemura binaphthol, nibindi.

Ibicuruzwa birambuye

Ibicuruzwa

Ibimenyetso bya Hazard C - Kubora
Kode y'ingaruka R34 - Bitera gutwikwa
Ibisobanuro byumutekano S26 - Mugihe uhuye namaso, kwoza ako kanya n'amazi menshi hanyuma ushakishe inama mubuvuzi.
S36 / 37/39 - Wambare imyenda ikingira, uturindantoki no kurinda amaso / mu maso.
S45 - Mugihe habaye impanuka cyangwa niba wumva utameze neza, shaka inama zubuvuzi ako kanya (erekana ikirango igihe cyose bishoboka.)
Indangamuntu ya Loni UN3259

 

Intangiriro

. Ibikurikira nintangiriro kumiterere yabyo, imikoreshereze, uburyo bwo gutegura n'umutekano:

 

Ubwiza:

 

Kugaragara: Ifu yera ya kristaline

Gukemura: gushonga muri alcool, ethers na ketone, kudashonga mumazi

Inzira ya molekulari: C14H16N2

Uburemere bwa molekuline: 212.29 g / mol

 

Gukoresha: (1S, 2S) -1,2-diphenylethylenediamine ifite uburyo bwinshi bwo gukoresha mubikorwa bya shimi na farumasi:

 

Chiral ligand: Ikora nka chiral ligand kandi irashobora gukoreshwa muguhindura synthesis ya asimmetric, cyane cyane muguhuza molekile ya chiral.

Irangi ryirangi: Irashobora gukoreshwa nkigihe gito muguhuza amarangi kama.

Umuringa-nikel ushyizwe hamwe: Irashobora kandi gukoreshwa nk'inyongera mugutegura umuringa-nikel.

 

Uburyo: (1S, 2S) -1,2-diphenylethylenediamine irashobora guhuzwa nintambwe zikurikira:

 

Sulfoxide chloride na fenylformaldehyde byongewe kuri Ethylene glycol dimethyl ether kugirango bibe diphenyl methanol.

Diphenylmethanol ikorwa na triethylamine muri acetonitrile kugirango itange (1S, 2S) -1,2-diphenylethylenediamine.

 

Umutekano: Gukoresha (1S, 2S) -1,2-diphenylethylenediamine bifite umutekano ugereranije iyo bikoreshejwe neza kandi bikabikwa. Nyamara, nkimiti iyo ari yo yose, iracyakeneye gukurikiza uburyo bukwiye bwo gukora laboratoire. Irinde guhura nuruhu n'amaso, kandi wirinde guhumeka cyangwa kumira. Uturindantoki turinda hamwe na gogles bigomba kwambarwa mugihe bikoreshwa, kandi bigakorerwa ahantu hafite umwuka mwiza. Mugihe habaye impanuka cyangwa guhumeka, shakisha ubuvuzi kandi utange amakuru kubyerekeye imiti.

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