Sodium borohydride (CAS # 16940-66-2)
Kode y'ingaruka | R60 - Birashobora kubangamira uburumbuke R61 - Birashobora guteza ingaruka mbi umwana utaravuka R15 - Guhura namazi birekura imyuka yaka cyane R34 - Bitera gutwikwa R23 / 24/25 - Uburozi muguhumeka, guhura nuruhu kandi niba byamizwe. R24 / 25 - R35 - Bitera gutwikwa cyane R21 / 22 - Byangiza guhura nuruhu kandi niba byamizwe. R51 / 53 - Uburozi bwibinyabuzima byo mu mazi, bushobora gutera ingaruka mbi zigihe kirekire mubidukikije byamazi. R42 / 43 - Birashobora gutera ubukangurambaga muguhumeka no guhuza uruhu. R49 - Irashobora gutera kanseri muguhumeka R63 - Ibyago bishobora kugirira nabi umwana utaravuka R62 - Ibyago bishoboka byuburumbuke R36 / 38 - Kurakaza amaso n'uruhu. R43 - Irashobora gutera sensibilisation ukoresheje uruhu R19 - Irashobora gukora peroxide iturika R68 - Ibyago bishoboka byingaruka zidasubirwaho R50 / 53 - Uburozi cyane ku binyabuzima byo mu mazi, bishobora gutera ingaruka mbi z'igihe kirekire mubidukikije. |
Ibisobanuro byumutekano | S53 - Irinde guhura - shaka amabwiriza yihariye mbere yo gukoresha. S43 - Mugihe cyo gukoresha umuriro… (hakurikiraho ubwoko bwibikoresho byo kurwanya umuriro bizakoreshwa.) S45 - Mugihe habaye impanuka cyangwa niba wumva utameze neza, shaka inama zubuvuzi ako kanya (erekana ikirango igihe cyose bishoboka.) S43A - S36 / 37/39 - Wambare imyenda ikingira, uturindantoki no kurinda amaso / mu maso. S26 - Mugihe uhuye namaso, kwoza ako kanya n'amazi menshi hanyuma ushakishe inama mubuvuzi. S22 - Ntugahumeke umukungugu. S50 - Ntukavange na… S36 / 37 - Wambare imyenda ikingira hamwe na gants. S61 - Irinde kurekura ibidukikije. Reba amabwiriza yihariye / impapuro z'umutekano. |
Indangamuntu ya Loni | UN 3129 4.3 / PG 3 |
WGK Ubudage | 2 |
RTECS | ED3325000 |
FLUKA BRAND F CODES | 10-21 |
TSCA | Yego |
Kode ya HS | 28500090 |
Icyiciro cya Hazard | 4.3 |
Itsinda ryo gupakira | I |
Uburozi | LD50 kumunwa murukwavu: 160 mg / kg LD50 dermal Urukwavu 230 mg / kg |
Intangiriro
Sodium borohydride nikintu kidasanzwe. Ni ifu ikomeye ishobora gushonga byoroshye mumazi kandi itanga igisubizo cya alkaline.
Sodium borohydride ifite imbaraga zo kugabanya kandi irashobora gukora hamwe nibintu byinshi kama. Ikoreshwa cyane muri synthesis organique kandi ikoreshwa kenshi nka hydrogenating agent. Sodium borohydride irashobora kugabanya aldehydes, ketone, esters, nibindi kuri alcool ihuye, kandi irashobora no kugabanya aside kuri alcool. Sodium borohydride irashobora kandi gukoreshwa muri decarboxylation, dehalogenation, denitrification nibindi reaction.
Gutegura sodium borohydride mubisanzwe tubona reaction ya borane nicyuma cya sodium. Ubwa mbere, icyuma cya sodiumi gisubizwa hamwe na hydrogène kugirango itegure hydride ya sodium, hanyuma igakorwa na trimethylamine borane (cyangwa triethylaminoborane) muri ether solvent kugirango ibone sodium borohydride.
Sodium borohydride nikintu gikomeye kigabanya imbaraga zifata vuba hamwe nubushuhe hamwe na ogisijeni mu kirere kugirango irekure hydrogen. Igikoresho kigomba gufungwa vuba kandi kigakomeza gukama mugihe gikora. Sodium borohydride nayo ikora byoroshye na acide kugirango irekure gaze ya hydrogène, kandi tugomba kwirinda guhura na acide. Sodium borohydride nayo ni uburozi, kandi ugomba kwitondera kwirinda guhumeka cyangwa guhura nuruhu. Mugihe ukoresheje sodium borohydride, ambara uturindantoki turinda ibirahure, hanyuma urebe ko icyo gikorwa gikorerwa ahantu hafite umwuka mwiza.