tert-butylmagnesium chloride （CAS # 677-22-5)
| Kode y'ingaruka | R12 - Biraka cyane R14 / 15 - R19 - Irashobora gukora peroxide iturika R22 - Byangiza niba byamizwe R34 - Bitera gutwikwa R66 - Guhura kenshi birashobora gutera uruhu cyangwa kumeneka R67 - Imyuka irashobora gutera gusinzira no kuzunguruka R15 - Guhura namazi birekura imyuka yaka cyane R11 - Biraka cyane R14 - Ifata cyane n'amazi R37 - Kurakaza sisitemu y'ubuhumekero R17 - Ubushake bwaka mu kirere R40 - Ibimenyetso bike byerekana ingaruka ziterwa na kanseri |
| Ibisobanuro byumutekano | S9 - Bika kontineri ahantu hafite umwuka mwiza. S16 - Irinde amasoko yo gutwikwa. S26 - Mugihe uhuye namaso, kwoza ako kanya n'amazi menshi hanyuma ushakishe inama mubuvuzi. S29 - Ntugasibe ubusa. S33 - Fata ingamba zo kwirinda ibicuruzwa bisohoka. S36 / 37/39 - Wambare imyenda ikingira, uturindantoki no kurinda amaso / mu maso. S43 - Mugihe cyo gukoresha umuriro… (hakurikiraho ubwoko bwibikoresho byo kurwanya umuriro bizakoreshwa.) S45 - Mugihe habaye impanuka cyangwa niba wumva utameze neza, shaka inama zubuvuzi ako kanya (erekana ikirango igihe cyose bishoboka.) |
| Indangamuntu ya Loni | UN 3399 4.3 / PG 1 |
| WGK Ubudage | 1 |
| FLUKA BRAND F CODES | 1-3-10 |
| Kode ya HS | 29319090 |
| Icyiciro cya Hazard | 4.3 |
| Itsinda ryo gupakira | I |
Intangiriro
gushonga -108 ℃ (Tetrahydrofuran)
Ubucucike 0.931g / mL kuri 25 c
Ingingo ya Flash 34 ° F.
Imiterere yo kubika 2-8 ° C.
Amazi ya Morphologiya
Ibara risobanutse neza ryijimye
Amazi adashobora kuboneka hamwe n'inzoga n'amazi.
Ibyiyumvo Umwuka & Ubushuhe
BRN 3535403
InChIKey ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Kwitegura
Gutegura tert-butyl magnesium chloride: Koresha sandpaper kugirango ukureho firime ya oxyde hejuru yumurongo wa magnesium hanyuma uyikatemo uduce twiza. Ibiro 3.6g (0,15 mol) bya chipi ya magnesium, byongewe kumutwe wamajosi ane ufite ibikoresho byo gukingira azote, stirrer, kondereseri hamwe na feri ihora itonyanga (umuyoboro wumye wa CaCl2 ushyirwa hejuru ya kondereseri) tube), yinjije azote mu icupa rya reaction mu gihe kingana niminota 10, ikuraho umwuka muri flask yamajosi ane, hanyuma ihindura umuvuduko wa azote, kandi ikomeza kwinjiza azote nto cyane. muri Sisitemu. 35 mL ya tetrahydrofuran itunganijwe yongewe kuri flask yamajosi ane, hanyuma hapimwa 13.9g (0,15 mol) ya tert-butyl chloride, hafi 3,5g ya tert-butyl chloride yongewe kumutwe wamajosi ane, hanyuma asigaye 10.4g ya tert-butyl chloride ivanze na mL 150 ya tetrahydrofuran itunganijwe hanyuma ikongerwaho kumuyoboro uhoraho utandukanya. Ongeramo ingano ntoya ya iyode, ishyushye gato, havuka umubare muto wibibyimba, ibara rya iyode iragabanuka, nibyiza ko sisitemu yogukora iteka gato nyuma yo gutangira, nyuma yo guta, kubyutsa kuri 3 ~ 4 h, kugeza chipi ya magnesium ibuze burundu, yerekana igisubizo kijimye.
amakuru yumutekano
Ibicuruzwa biteye akaga biranga f, c, f
Icyiciro cya kode 12-14 / 15-19-22-34-66-67-15-11-14-37-17-40
Amabwiriza yumutekano 9-16-26-29-33-36 / 37 / 39-43-45
Gutwara ibicuruzwa biteje akaga UN 3399 4.3 / PG 1
WGK Ubudage 1
F 1-3-10
HazardClass 4.3
Gupakira Itsinda I.
Kode ya gasutamo 29319090
